Rubber-metal bonding as an electrochemical process

被引:0
|
作者
Hummel, K [1 ]
Filimonov, A [1 ]
Hobisch, J [1 ]
Rodriguez, FJS [1 ]
机构
[1] Graz Tech Univ, Inst Chem Technol Org Stoffe, A-8010 Graz, Austria
来源
KAUTSCHUK GUMMI KUNSTSTOFFE | 2000年 / 53卷 / 11期
关键词
rubber-metal bonding; electrochemistry; NR; SBR; brass; aluminium;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Rubber-brass bonding during vulcanization has already been previously discussed as a result of ionic reaction mechanisms. If electrically charged species (e.g. metal and sulfide ions) are formed, the bonding process should be influenced by an electric field. An experimental set-up for the application of a voltage during vulcanization and the preparation of test specimens for bonding strength measurements is described. Electric conductivity is brought about by the carbon black component. Indeed, experiments with SBR mixtures/brass show that an electric field influences the bonding process and that under suitable conditions an improvement of the bonding strength is observed. Unexpectedly rubber-metal bonding is also observed with NR mixtures/aluminium (alloy with 5% silicon) when a voltage is applied.
引用
收藏
页码:651 / 655
页数:5
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