Palladium-catalyzed arylation of cyclopentadienes

被引：0

作者：

Dyker, G

Heiermann, J

Miura, M

Inoh, JI

Pivsa-Art, S

Satoh, T

Nomura, M

机构：

[1] Univ Duisburg, Fb 6, D-47048 Duisburg, Germany

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2000年 / 6卷 / 18期

关键词：

domino reactions; extended pi-systems; palladium catalysis; rotamers;

D O I：

10.1002/1521-3765(20000915)6:18<3426::AID-CHEM3426>3.0.CO;2-B

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclopentadiene and metallocenes, typically zirconocene dichloride, are suitable substrates for multiple arylations with aryl bromides in palladium-catalyzed reactions. Thus, various aryl bromides bearing either an electron-donating or an electron-withdrawing substituent can react with these substrates to afford the corresponding 1,2,3,4,5-pentaaryl-13-cyclopentadienes in a single preparative step. Derivatives of cyclopentadiene. including di- and trisubstituted cyclopentadienes. and indene are arylated in a similar fashion.

引用

页码：3426 / 3433

页数：8

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