Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate

被引：4
|
作者：
Safo, Martin K. [1 ]
Buentello, Kristin E. [1 ]
Oliver, Allen G. [1 ]
Scheidt, W. Robert [1 ]
机构：
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1107/S1600536810020015
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title molecule, [Fe(C36H44N4)Cl] ·1.5CH2Cl2, is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.
引用
收藏
页码：M733 / U224
页数：12
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