Transfer Enthalpies of Glycine in Aqueous Amide Derivatives Solutions

被引：0

作者：

Liu Chunli ^{[1
]}

Ma Lin ^{[2
]}

Lin Ruisen ^{[3
]}

机构：

[1] Zaozhuang Coll, Dept Chem & Chem Engn, Zaozhuang 277160, Peoples R China

[2] Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Peoples R China

[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

ACTA CHIMICA SINICA | 2009年 / 67卷 / 24期

关键词：

glycine; enthalpy of transfer; amide derivative; PARTIAL MOLAR VOLUMES; ALPHA-AMINO-ACIDS; 298.15; K; WATER; 25-DEGREES-C; SOLVATION; INTERPLAY; PEPTIDES; NANO3; LINO3;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enthalpies of solution of glycine in aqueous solutions of N-methylformamide (NMF), N,N-dimethylformamide (DMF), N-methylacetamide (NMA) and N,N-dimethylacetamide (DMA) have been determined at T=298.15 K by an RD496-II microcalorimeter. The enthalpies of transfer of glycine from water to the aqueous solutions of amide derivatives were derived and discussed in terms of a structural hydration interaction model. The values of Delta H-tr are positive and increase overall with increasing the concentration of amides. The relative order of Delta H-tr from water to the aqueous solutions of formamide (FA), acetamide (AD) and the four derivatives is DMA>NMA>DMF>NMF>AD>FA. The results suggest that in formamide solutions hydrophilic-hydrophilic interaction is responsible for the trends, while in other amide solutions hydrophilic-hydrophobic interaction is predominant.

引用

页码：2875 / 2878

页数：4

共 15 条

[1] Monte Carlo investigations of intermolecular interactions in water-amide mixtures
Cordeiro, MAM
Santana, WP
Cusinato, R
Cordeiro, JMM
[J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2006, 759 (1-3): : 159 - 164
[2] APPARENT MOLAL VOLUMES OF ALKALI HALIDES IN WATER AT 25 DEGREES . INFLUENCE OF STRUCTURAL HYDRATION INTERACTIONS ON CONCENTRATION DEPENDENCE
DESNOYER.JE
AREL, M
PERRON, G
JOLICOEU.C
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (10): : 3346 - &
[3] Enthalpy of interaction of some amides with ammonium methanoate in water at 25 degrees C - Interactions between ionic groups and peptide and hydrophobic groups
Fernandez, J
GarciaLisbona, MN
Lilley, TH
Linsdell, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (03): : 407 - 411
[4] THE ENTHALPY OF SOLUTION OF SRM-1655 (KCL) IN H2O
KILDAY, MV
[J]. JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1980, 85 (06): : 467 - 481
[5] THE INTERPLAY BETWEEN SOLUTE SOLVATION AND SOLUTE SOLUTE INTERACTIONS IN SOLUTIONS CONTAINING AMINO-ACIDS, PEPTIDES AND RELATED SPECIES
LILLEY, TH
[J]. PURE AND APPLIED CHEMISTRY, 1993, 65 (12) : 2551 - 2560
[6] INTERACTIONS IN SOLUTIONS - THE INTERPLAY BETWEEN SOLUTE SOLVATION AND SOLUTE SOLUTE INTERACTIONS
LILLEY, TH
[J]. PURE AND APPLIED CHEMISTRY, 1994, 66 (03) : 429 - 434
[7] Liu CL, 2008, ACTA CHIM SINICA, V66, P1632
[8] Liu CL, 2007, ACTA CHIM SINICA, V65, P998
[9] Enthalpies of transfer of amino acids from water to aqueous solutions of alkali metal nitrates
Liu, CL
Lin, RS
Xu, N
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (06): : 2094 - 2096
[10] Enthalpy of transfer of amino acids from water to aqueous glucose solutions at 298.15 K
Lou, Y
Lin, RS
[J]. THERMOCHIMICA ACTA, 1998, 316 (02) : 145 - 148

← 1 2 →