Improvement of anaerobic digestion of sewage sludge through microwave pre-treatment

被引:52
|
作者
Serrano, A. [1 ]
Siles, J. A. [1 ]
Martin, M. A. [1 ]
Chica, A. F. [1 ]
Estevez-Pastor, F. S. [2 ]
Toro-Baptista, E. [2 ]
机构
[1] Univ Cordoba, Dept Inorgan Chem & Chem Engn, Campus Univ Rabanales,Edificio Marie Curie C-3, E-14071 Cordoba, Spain
[2] SA EMASESA, Empresa Metropolitana Aguas Sevilla, C Escuelas Pias 1, Seville 41008, Spain
关键词
Microwave pre-treatment; Mesophilic anaerobic digestion; Optimization; Sewage sludge; Specific energy applied; Kinetics; SECONDARY SLUDGE;
D O I
10.1016/j.jenvman.2016.03.048
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Sewage sludge generated in the activated sludge process is a polluting waste that must be treated adequately to avoid important environmental impacts. Traditional management methods, such as landfill disposal or incineration, are being ruled out due to the high content in heavy metal, pathogens, micropolluting compounds of the sewage sludge and the lack of use of resources. Anaerobic digestion could be an interesting treatment, but must be improved since the biomethanisation of sewage sludge entails low biodegradability and low methane production. A microwave pre-treatment at pilot scale is proposed to increase the organic matter solubilisation of sewage sludge and enhance the biomethanisation yield. The operational variables of microwave pre-treatment (power and specific energy applied) were optimised by analysing the physicochemical characteristics of sewage sludge (both total and soluble fraction) under different pre-treatment conditions. According to the variation in the sCOD and TN concentration, the optimal operation variables of the pre-treatment were fixed at 20,000 J/g TS and 700 W. A subsequent anaerobic digestion test was carried out with raw and pre-treated sewage sludge under different conditions (20,000 J/g TS and 700 W; 20,000 J/g TS and 400 W; and 30,000 J/g TS and 400 W). Although stability was maintained throughout the process, the enhancement in the total methane yield was not high (up to 17%). Nevertheless, very promising improvements were determined for the kinetics of the process, where the r(G) and the OLR increased by 43% and 39%, respectively, after carrying out a pre-treatment at 20,000 J/g TS and 700 W. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:231 / 239
页数:9
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