Determination of the stability constants of Pu(VI) carbonate complexes by capillary electrophoresis coupled with inductively coupled plasma mass spectrometer

被引：4

作者：

Alexandre, Jean-Charles ^{[1
,2
]}

Dacheux, Nicolas

Aupiais, Jean ^{[1
,2
]}

机构：

[1] CEA, DAM, DIF, F-91297 Arpajon, France

[2] Univ Montpellier, ENSCM, ICSM, CEA,CNRS,Site Marcoule, F-30207 Bagnols Sur Ceze, France

来源：

RADIOCHIMICA ACTA | 2018年 / 106卷 / 10期

关键词：

Radiochemistry; environment; speciation of actinides; plutonium hexavalent; carbonate ligand; capillary electrophoresis; ICP-MS; EQUILIBRIA; SPECIATION; U(VI); NP(V); MS;

D O I：

10.1515/ract-2018-2929

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New determination of the stability constants related to the Pu(VI)/carbonate chemical system has been obtained by coupling capillary electrophoresis and ICP-MS at the ionic strength of 0.202 m in NaClO4 and for a temperature of 25 degrees C. The following values have been obtained: log(10) beta(PuO2CO3) = 8.12 +/- 0.02, log(10) beta(PuO2(CO3)22-) = 13.96 +/- 0.04, and log(10) beta(PuO2(CO3)34) = 18.10 +/- 0.03. Based on the values selected by AEN/OECD, the interaction coefficients have been re-evaluated as follows: epsilon(PuO2CO3) = 0.02 +/- 0.21, epsilon(PuO2(CO3)22-,Na+) = 0.12 +/- 0.08, and epsilon(PuO2(CO3)34-,Na+) = 0.14 +/- 0.18 kg.mol(-1).

引用

页码：801 / 807

页数：7

共 50 条

[1] Capillary electrophoresis inductively coupled plasma mass spectrometry
Majidi, V
MICROCHEMICAL JOURNAL, 2000, 66 (1-3) : 3 - 16
[2] Determination of cobalamins using capillary electrophoresis inductively coupled plasma mass spectrometry
Baker, SA
Miller-Ihli, NJ
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2000, 55 (12) : 1823 - 1832
[3] Determination of the Stability Constants of the Acetate Complexes of the Actinides Am(III), Th(IV), Np(V), and U(VI) Using Capillary Electrophoresis-Inductively Coupled Plasma Mass Spectrometry
Willberger, Christian
Leichtfuss, Daniel
Amayri, Samer
Reich, Tobias
INORGANIC CHEMISTRY, 2019, 58 (08) : 4851 - 4858
[4] Determination of monophosphate nucleotides by capillary electrophoresis inductively coupled plasma mass spectrometry
Yeh, CF
Jiang, SJ
ANALYST, 2002, 127 (10) : 1324 - 1327
[5] Interfacing capillary electrophoresis with inductively coupled plasma mass spectrometry
Karen, I
Caruso, JA
LC GC-MAGAZINE OF SEPARATION SCIENCE, 1999, 17 (01): : 36 - +
[6] Actinide oxalate complexes formation as a function of temperature by capillary electrophoresis coupled with inductively coupled plasma mass spectrometry
Brunel, Benoit
Philippini, Violaine
Mendes, Mickael
Aupiais, Jean
RADIOCHIMICA ACTA, 2015, 103 (01) : 27 - 37
[7] Inductively coupled plasma mass spectrometric detection for chromatography and capillary electrophoresis
Sutton, K
Sutton, RMC
Caruso, JA
JOURNAL OF CHROMATOGRAPHY A, 1997, 789 (1-2) : 85 - 126
[8] Capillary electrophoresis - Inductively coupled plasma mass spectrometry for elemental speciation
Olesik, JW
Grunwald, EJ
Kinzer, JA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 182 - ANYL
[9] Interface for the coupling of capillary electrophoresis and inductively coupled plasma mass spectrometry
Tangen, A
Lund, W
Josefsson, B
Borg, H
JOURNAL OF CHROMATOGRAPHY A, 1998, 826 (01) : 87 - 94
[10] Determination of mercury compounds by capillary electrophoresis inductively coupled plasma mass spectrometry with microconcentric nebulization
Lee, TH
Jiang, SJ
ANALYTICA CHIMICA ACTA, 2000, 413 (1-2) : 197 - 205

← 1 2 3 4 5 →