First total synthesis of valeriananoid A

被引：10
|
作者：
Hagiwara, H
Morii, A
Yamada, Y
Hoshi, T
Suzuki, T
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[2] Niigata Univ, Fac Engn, Dept Chem & Chem Engn, Niigata 9502181, Japan
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 08期
关键词：
bicyclic aliphatic compounds; domino Michael reactions; sesquiterpenenoid; valeriananoid;
D O I：
10.1016/S0040-4039(03)00064-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A tricyclic sesquiterpenoid, valeriananoid A 1, has been synthesized via domino Michael reaction of oxophorone 4 and subsequent 6-endo-trig cyclization of a ketyl radical as key steps. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1595 / 1597
页数：3
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