Structure, H-1 NMR spectra, thermodynamics, and transport properties of molten salt solutions .1. 4-Methylpyridinium chloride and 4-methylpyridinium iodine

被引:4
|
作者
Newman, DS [1 ]
Potter, M [1 ]
Fang, L [1 ]
Davy, R [1 ]
Parker, F [1 ]
机构
[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109
关键词
D O I
10.1149/1.1836406
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The H-1 NMR spectra of binary mixtures of 4-methylpyridinium chloride and 4-methylpyridinium iodide were measured as a function of temperature and composition over the entire composition range. Correlations were made between these spectra and thermodynamic and transport properties of the melts. The effect of hydrogen bonding on the melt's properties was assessed and a four ''component'' model was proposed to account for these properties. A pronounced ''mixed ion'' effect was observed in the NMR spectra, but was barely discernible in the transport properties and completely absent in the thermodynamic properties.
引用
收藏
页码:183 / 189
页数:7
相关论文
共 50 条
  • [1] CORRELATIONS BETWEEN EQUIVALENT CONDUCTANCE AND H-1NMR SPECTROSCOPY IN MOLTEN 4-METHYLPYRIDINIUM HALIDES
    NEWMAN, DS
    BANJOKO, O
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (08) : C369 - C369
  • [2] 1-(4-Cyanobenzyl)-4-methylpyridinium bromide
    Chen, Hong
    Zhu, Kun
    Liu, Guang-Xiang
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1453 - U1425
  • [3] THE RELATIONSHIP OF TRANSPORT-PROPERTIES AND H-1-NMR SPECTRA TO THE STRUCTURE OF MOLTEN METHYLPYRIDINIUM HALIDES
    NEWMAN, DS
    RHINEBARGER, RR
    SICONOLFI, D
    BANJOKO, OA
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (11) : 2331 - 2336
  • [4] Synthesis and nonlinear properties of poly[1,4-bis(4-methylpyridinium)butadiyne triflate)]
    Shiga, K
    Inoguchi, T
    Mori, K
    Kondo, K
    Kamada, K
    Tawa, K
    Ohta, K
    Maruo, T
    Mochizuki, E
    Kai, Y
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (02) : 257 - 262
  • [5] CORRELATIONS BETWEEN TRANSPORT-PROPERTIES, H-1-NMR SPECTRA, AND STRUCTURE OF MOLTEN METHYLPYRIDINIUM IODIDES
    NEWMAN, DS
    STEVENS, R
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (08) : C409 - C409
  • [6] Synthesis, thermal stability, crystal structure and optical properties of 1,1′-(1,n-alkanediyl)bis(4-methylpyridinium) bromobismuthates
    Kotov, Vitaiii Yu.
    Ilyukhin, Andrey B.
    Simonenko, Nikolai P.
    Kozyukhin, Sergey A.
    [J]. POLYHEDRON, 2017, 137 : 122 - 126
  • [7] Structure, Physicochemical and Biological Properties of an Aqua (2,2′,2"-Nitrilotriacetato)-oxidovanadium(IV) Salt with 4-Methylpyridinium Cation
    Tesmar, Aleksandra
    Wyrzykowski, Dariusz
    Kazimierczuk, Katarzyna
    Klak, Julia
    Kowalski, Szymon
    Inkielewicz-Stepniak, Iwona
    Drzezdzon, Joanna
    Jacewicz, Dagmara
    Chmurzynski, Lech
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (07): : 501 - 510
  • [8] 1-(4-Cyanobenzyl)-4-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III)
    Liu, Guang-Xiang
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1707 - U1158
  • [9] Growth aspects, structural and nonlinear optical properties of conjugate structure: 4-methylpyridinium 2-carboxy-6-nitrobenzoate
    Reena Devi S.
    Suresh S.
    Vinitha G.
    Mohan Kumar R.
    [J]. Mohan Kumar, R. (mohan66@hotmail.com), 2018, Optical Society of India (47): : 516 - 526
  • [10] An anion-radical salt of 1-(4-cyanobenzyl)-4-methylpyridinium cations and 7,7,8,8-tetracyanoquinodimethane anions
    Wang, Peng-Fei
    Zhou, Hong-Bo
    Chen, You-Cun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1110 - o1112