Structural control of silver(I) coordination polymers: construction of two- and three-dimensional frameworks of silver(I) ions bridged by dicyanopyrazine derivatives

被引：13

作者：

Suenaga, Y ^{[1
]}

Kamiya, T

Kuroda-Sowa, T

Maekawa, M

Munakata, M

机构：

[1] Kinki Univ, Dept Chem, Higashiosaka, Osaka 5778502, Japan

[2] Kinki Univ, Res Inst Sci & Technol, Higashiosaka, Osaka 5778502, Japan

来源：

INORGANICA CHIMICA ACTA | 2000年 / 308卷 / 1-2期

关键词：

crystal structures; silver complexes; coordination polymer complexes;

D O I：

10.1016/S0020-1693(00)00221-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The silver(I) complexes of pyrazine-2,3-dicarbonitrile (2,3-dcpz), [Ag(2,3-dcpz)(ClO4)] (1a) and pyrazine-2,5-dicarbonitrile (2,5-dcpz), [Ag(2,5-dcpz)(X)] (2a: X=ClO4, 2b: X = CF3SO3) have been prepared and their molecular structure has been determined by X-ray crystallography. The silver ion in la prefers an octahedral coordination geometry and forms a two-dimensional square mesh structure. On the other hand, the silver ion in both 2a and 2b prefers a distorted square pyramidal coordination geometry that forms a three-dimensional structure with a cavity. By changing the bridging angle of the ligands and the size of the solvent, we could successfully control the crystal structure of the silver(I) coordination polymers. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：17 / 21

页数：5

共 50 条

[1] Structural control of copper(I) coordination polymers: Construction of one-, two-, and three-dimensional frameworks of tetrahedral copper(I) ions bridged by dicyanobenzene derivatives
Kuroda-Sowa, T
Horino, T
Yamamoto, M
Ohno, Y
Maekawa, H
Munakata, M
[J]. INORGANIC CHEMISTRY, 1997, 36 (27) : 6382 - 6389
[2] Photoluminescent two-dimensional coordination polymers constructed with octanuclear silver(I) clusters or silver(I) ions
Tong, ML
Shi, JX
Chen, XM
[J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (07) : 814 - 816
[3] Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different silver(I) salts
Tong, ML
Zheng, SL
Chen, XM
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2000, 6 (20) : 3729 - 3738
[4] Assembly of Silver(I) Two- and Three-Dimensional Coordination Networks with Complementary Tridentate Heteroaryl Ethynide Ligands
Zhao, Liang
Mak, Thomas C. W.
[J]. INORGANIC CHEMISTRY, 2009, 48 (14) : 6480 - 6489
[5] Construction of two- and three-dimensional coordination polymers from cobalt trimesate
Livage, C
Guillou, N
Marrot, J
Férey, G
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (11) : 4387 - 4392
[6] Effect of synthetic conditions on the structures of silver(I)-hexamethylenetetramine coordination polymers: crystal structures of two three-dimensional frameworks featuring new topological motifs
Zheng, SL
Zhang, JP
Chen, XM
Ng, SW
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) : 45 - 52
[7] Two- and Three-Dimensional Silver(I)-Organic Networks Generated from Mono- and Dicarboxylphenylethynes
Zhao, Ying
Zhang, Peng
Li, Bao
Meng, Xianggao
Zhang, Tianle
[J]. INORGANIC CHEMISTRY, 2011, 50 (18) : 9097 - 9105
[8] One-, Two-, and Three-Dimensional Coordination Polymers of Stilbenedicarboxylate with Different Metal Ions
Ma, Yu
Cheng, Ai-Ling
Zhang, Jian-Yong
Yue, Qi
Gao, En-Qing
[J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (02) : 867 - 873
[9] Structural and spectroscopic studies of three novel two- and three-dimensional coordination polymers with benzenetricarboxylate ligands
do Carmo, Weberton R.
Franco, Chris Hebert J.
Diniz, Renata
[J]. INORGANICA CHIMICA ACTA, 2012, 385 : 119 - 127
[10] One-, two- and three-dimensional copper(I) and silver(I) complexes of 2,11-dithia[3.3]paracyclophane
Munakata, M
Wu, LP
KurodaSowa, T
Maekawa, M
Suenaga, Y
Nakagawa, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (08): : 1525 - 1530

← 1 2 3 4 5 →