Kinetics of isothermal and non-isothermal precipitation in an Al-6 at% Si alloy

被引:0
|
作者
Starink, MJ [1 ]
Zahra, AM [1 ]
机构
[1] CNRS, Ctr Thermodynam & Microcalorimetrie, F-13331 Marseille 3, France
来源
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES | 1998年 / 77卷 / 01期
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中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel theory which describes the progress of a thermally activated reaction under isothermal and linear heating conditions is presented. It incorporates nucleation, growth and impingement and takes account of temperature-dependent solubility. The model generally fits very well to isothermal calorimetry and differential scanning calorimetry data on precipitation in an Al-6 at.% Si alloy. Analysis of the data shows that two processes occur in this precipitation reaction: growth of large Si particles and growth of pre-existing small nuclei. Determination of the sizes of Si precipitates by transmission electron microscopy indicates that interfacial energy contributions are small and have a negligible influence on solubility.
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页码:187 / 199
页数:13
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