Synthetic receptors based on calix[4]arene functionalized at the lower rim in molecular recognition of dicarboxylic, α-hydroxycarboxylic, and α-amino acids

被引：11

作者：

Stoikov, II ^{[1
]}

Gafiullina, LI ^{[1
]}

Ibragimova, DS ^{[1
]}

Antipin, IS ^{[1
]}

Konovalov, AI ^{[1
]}

机构：

[1] Kazan VI Lenin State Univ, Kazan 420008, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

calix[4]arene; thiacalix[4]arene; membrane transport; dicarboxylic acids; alpha-hydroxycarboxylic acids; carboxylate anions; synthetic receptors; molecular recognition;

D O I：

10.1023/B:RUCB.0000042270.26330.cb

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New calix[4]arenes, di- and tetrasubstituted at the lower rim, with different functional groups were synthesized. They were studied as carriers of a series of dicarboxylic and alpha-hydroxycarboxylic acids through a liquid impregnated membrane. The calix[4]arenes under study are capable of molecular recognition of oxalic acid in the series of structurally similar dicarboxylic and (alpha-hydroxycarboxylic acids. The regularities found make it possible to change purposefully the receptor ability of 1,3-disubstituted calix[4]arenes by variation of the nature of substituents.

引用

页码：1172 / 1180

页数：9

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