MnO2 Nanoparticles Confined in TiO2 Nanotubes for Catalytic Combustion of Butane

被引:14
|
作者
Zhang, Sen [1 ,2 ]
Luo, Weimin [1 ]
Yang, Xu [1 ]
Lv, Tai [2 ]
Huang, Yanqin [1 ]
Dong, Kaijun [1 ]
Li, Xinjun [1 ]
机构
[1] Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
[2] Northeast Elect Power Univ, Dept Thermal Energy & Power Engn, Jilin 132012, Jilin, Peoples R China
来源
CHEMISTRYSELECT | 2017年 / 2卷 / 16期
基金
中国国家自然科学基金;
关键词
Butane; Catalytic combustion; Confinement effect; MnO2; TiO2; nanotubes; VOLATILE ORGANIC-COMPOUNDS; MANGANESE OXIDES; TOTAL OXIDATION; CARBON NANOTUBES; HYDROCARBONS; REDUCTION; BEHAVIOR; REMOVAL; TOLUENE;
D O I
10.1002/slct.201700299
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A confined MnO2 catalyst with MnO2 nanoparticles entrapped in TiO2 nanotube was synthesized through vacuum-assisted impregnation method. Due to the confinement effect of TiO2 nanotube, the electron density distribution between the exterior and interior nanotube surface is modulated. As such, the confined MnO2 can facilitate the formation and migration of active oxygen species in the catalyst. The catalyst exhibits the enhanced activity in the catalytic combustion of butane, and the reaction temperature is significantly lowered. This result demonstrates that the confined MnO2 in TiO2 nanotube can serve as a cost-effective catalyst for the elimination of VOCs from the air.
引用
收藏
页码:4557 / 4560
页数:4
相关论文
共 50 条
  • [1] Pd nanoparticles entrapped in TiO2 nanotubes for complete butane catalytic combustion at 130 °C
    Xu Yang
    Xueyi Lu
    Liangpeng Wu
    Jiafeng Zhang
    Yanqin Huang
    Xinjun Li
    Environmental Chemistry Letters, 2017, 15 : 421 - 426
  • [2] Pd nanoparticles entrapped in TiO2 nanotubes for complete butane catalytic combustion at 130 A°C
    Yang, Xu
    Lu, Xueyi
    Wu, Liangpeng
    Zhang, Jiafeng
    Huang, Yanqin
    Li, Xinjun
    ENVIRONMENTAL CHEMISTRY LETTERS, 2017, 15 (03) : 421 - 426
  • [3] Catalytic ozonation of oxalic acid with MnO2/TiO2 and Rh/TiO2
    Quispe, Cristina
    Villasenor, Jorge
    Pecchi, Gina
    Reyes, Patricio
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2006, 51 (04): : 1049 - 1052
  • [4] The effect of CuO modification for a TiO2 nanotube confined CeO2 catalyst on the catalytic combustion of butane
    Yao, Guansheng
    Wu, Liangpeng
    Lv, Tai
    Li, Juan
    Huang, Yanqin
    Dong, Kaijun
    Li, Xinjun
    OPEN CHEMISTRY, 2018, 16 (01): : 1 - 8
  • [5] CATALYTIC EFFECTS OF TIO2 AND MNO2 ON THE PHASE TRANSFORMATION OF GOTHITE
    CHAKRABORTY, SC
    ROY, A
    JOURNAL OF CHEMICAL PHYSICS, 1956, 25 (05): : 1079 - 1080
  • [6] Thermophysical and Electrical Properties of MnO2 and TiO2 Nanotubes Dispersed Transformer Oil
    Aravind, S. S. Jyothirmayee
    Baskar, Prathab
    Das, Sumitesh
    Ramaprabhu, S.
    JOURNAL OF NANOFLUIDS, 2014, 3 (03) : 217 - 222
  • [7] Pt nanoparticles Confined in TiO2 Nanotubes With Enhanced Catalytic Performance for Phenol Hydrogenation by Atomic Layer Deposition
    Wang, Meihua
    Yang, Wen
    CATALYSIS LETTERS, 2022, 152 (04) : 1020 - 1028
  • [8] Decomposition of hydrogen peroxide on MnO2/TiO2 catalysts
    Sorge, AR
    Turco, M
    Pilone, G
    Bagnasco, G
    JOURNAL OF PROPULSION AND POWER, 2004, 20 (06) : 1069 - 1075
  • [9] Enhanced activity for catalytic combustion of ethylene by the Pt nanoparticles confined in TiO2 nanotube with surface oxygen vacancy
    Wang, Xiaoyang
    Lian, Mengjie
    Yang, Xu
    Lu, Peng
    Zhou, Jianhua
    Gao, Jie
    Liu, Chengyan
    Liu, Wenping
    Miao, Lei
    CERAMICS INTERNATIONAL, 2022, 48 (03) : 3933 - 3940
  • [10] Growth of MnO2 nanoflakes on TiO2 nanorods for pseudocapacitor
    Mo, Liuye
    Zheng, Haitao
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 788 : 1162 - 1168