NH3-SCR on Fe zeolite catalysts - From model setup to NH3 dosing

被引：55
|
作者：
Schuler, A. [1 ]
Votsmeier, M. [2 ]
Kiwic, P. [3 ]
Gieshoff, J. [2 ]
Hautpmann, W. [2 ]
Drochner, A. [1 ]
Vogel, H. [1 ]
机构：
[1] Tech Univ Darmstadt, Ernst Berl Inst, D-64287 Darmstadt, Germany
[2] Umicore AG & Co KG, D-63457 Hanau, Germany
[3] ETH, Inst Measurement & Control, CH-8092 Zurich, Switzerland
来源：
CHEMICAL ENGINEERING JOURNAL | 2009年 / 154卷 / 1-3期
关键词：
Fe exchanged zeolite; SCR; NH3; Ammonia; dosing; Control; Standard SCR Reaction; Fast SCR Reaction; NO2 SCR Reaction; NITRIC-OXIDE; FE-ZSM-5; CATALYST; EXCHANGED ZSM-5; DIESEL EXHAUST; REDUCTION; AMMONIA; SCR; NO; TEMPERATURE;
D O I：
10.1016/j.cej.2009.02.037
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The setup of a detailed model for the NH3-SCR process on iron exchanged zeolite catalysts is described, which takes into account the reactions of NH3, NO and NO2 occurring under typical exhaust conditions. Validation experiments fora standard SCR gas mixture show that the model is able to describe the dynamic behaviour of this system at transient temperature conditions. The model is used for the parameterization of an ammonia dosing controller. To prove the functionality of this controller it was implemented on a synthetic gas test bench and tested by a dynamic temperature experiment. This setup allows the evaluation of the parameterized controller without any disturbances from engine or injection effects. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：333 / 340
页数：8
相关论文
共 50 条
  • [1] Fe-BEA Zeolite Catalysts for NH3-SCR of NOx
    Anne Mette Frey
    Selcuk Mert
    Johannes Due-Hansen
    Rasmus Fehrmann
    Claus Hviid Christensen
    Catalysis Letters, 2009, 130 : 1 - 8
  • [2] Fe-BEA Zeolite Catalysts for NH3-SCR of NOx
    Frey, Anne Mette
    Mert, Selcuk
    Due-Hansen, Johannes
    Fehrmann, Rasmus
    Christensen, Claus Hviid
    CATALYSIS LETTERS, 2009, 130 (1-2) : 1 - 8
  • [3] New insights into NH3/NO chemisorption properties and NH3-SCR reaction mechanism over Cu/SAPO-34 as NH3-SCR catalysts
    Wang, Lei
    Li, Wei
    Qi, Gongshin
    Weng, Duan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [4] Alkali Resistant Fe-Zeolite Catalysts for SCR of NO with NH3 in Flue Gases
    Putluru, Siva Sankar Reddy
    Jensen, Anker Degn
    Riisager, Anders
    Fehrmann, Rasmus
    TOPICS IN CATALYSIS, 2011, 54 (16-18) : 1286 - 1292
  • [5] Alkali Resistant Fe-Zeolite Catalysts for SCR of NO with NH3 in Flue Gases
    Siva Sankar Reddy Putluru
    Anker Degn Jensen
    Anders Riisager
    Rasmus Fehrmann
    Topics in Catalysis, 2011, 54
  • [6] Formation and Effect of NH4+ Intermediates in NH3-SCR over Fe-ZSM-5 Zeolite Catalysts
    Chen, Peirong
    Jablonska, Magdalena
    Weide, Philipp
    Caumanns, Tobias
    Weirich, Thomas
    Muhler, Martin
    Moos, Ralf
    Palkovits, Regina
    Simon, Ulrich
    ACS CATALYSIS, 2016, 6 (11): : 7696 - 7700
  • [7] In Situ Spectroscopic Studies of Proton Transport in Zeolite Catalysts for NH3-SCR
    Chen, Peirong
    Simon, Ulrich
    CATALYSTS, 2016, 6 (12)
  • [8] Radio-Frequency-Controlled Urea Dosing for NH3-SCR Catalysts: NH3 Storage Influence to Catalyst Performance under Transient Conditions
    Dietrich, Markus
    Hagen, Gunter
    Reitmeier, Willibald
    Burger, Katharina
    Hien, Markus
    Grass, Philippe
    Kubinski, David
    Visser, Jaco
    Moos, Ralf
    SENSORS, 2017, 17 (12)
  • [9] Design of a "high-efficiency" NH3-SCR reactor for stationary applications. A kinetic study of NH3 oxidation and NH3-SCR over V-based catalysts
    Usberti, Nicola
    Jablonska, Magdalena
    Di Blasi, Miriam
    Forzatti, Pio
    Lietti, Luca
    Beretta, Alessandra
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 179 : 185 - 195
  • [10] Inhibitory role of excessive NH3 in NH3-SCR on CeWOx at low temperatures
    Liu, Kuo
    Huo, Yanlong
    Yan, Zidi
    Shan, Wenpo
    He, Hong
    CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (09) : 2758 - 2762
12345