Synthesis and self-assembly of functionalized donor-σ-acceptor molecules

被引：43
|
作者：
Li, HF [1 ]
Homan, EA [1 ]
Lampkins, AJ [1 ]
Ghiviriga, I [1 ]
Castellano, RK [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 03期
关键词：
D O I：
10.1021/ol047597y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
3,5,7-Tris(arylmethyl)-1-aza-adamantanetrione donor-alpha-acceptor compounds have been synthesized in four steps. Computational and H-1 NMR analyses rationalize the solubility, gelation, and conformational properties of the C-3-symmetric molecules toward employing sigma-coupled donor-acceptor interactions in molecular self-assembly.
引用
收藏
页码：443 / 446
页数：4
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