1D Mn(iii) coordination polymers exhibiting chiral symmetry breaking and weak ferromagnetism

被引：2

作者：

Hara, Aoi ^{[1
]}

Kusumoto, Sotaro ^{[1
]}

Sekine, Yoshihiro ^{[1
,2
]}

Harrowfield, Jack ^{[3
]}

Kim, Yang ^{[1
]}

Hayami, Shinya ^{[1
,4
]}

Nakamura, Masaaki ^{[1
]}

机构：

[1] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan

[2] Kumamoto Univ, Prior Org Innovat & Excellence, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan

[3] Univ Strasbourg, ISIS, 8 Allee Gaspard Mange, F-67083 Strasbourg, France

[4] Kumamoto Univ, Inst Ind Nanomat IINa, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 16期

关键词：

Ferromagnetism - Manganese compounds - Coordination reactions;

D O I：

10.1039/d1dt00569c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mn(iii) complexes with achiral ligands, (E)-N-(2-((2-aminobenzylidene)amino)-2-methylpropyl)-5-X-2-hydroxybenzamide (HLX, X = H, Cl, Br, and I), crystallise as chiral conglomerates containing amide oxygen-bridged one-dimensional coordination polymers that exhibit weak ferromagnetism. The bulk products exhibit symmetry breaking in that they do not contain equal amounts of enantiomers, though which is the dominant species depends on the substituent X.

引用

页码：5428 / 5432

页数：5

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