Antimony(III) and bismuth(III) amides containing pendant N-donor groups - a combined experimental and theoretical study

被引：8

作者：

Vranova, Iva ^{[1
]}

Jambor, Roman ^{[1
]}

Ruzicka, Ales ^{[1
]}

Hoffmann, Alexander ^{[2
]}

Herres-Pawlis, Sonja ^{[2
]}

Dostal, Libor ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic

[2] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 01期

关键词：

BOND COVALENT RADII; PHOSPHINE COMPLEXES; ORGANOBISMUTH(III) DIHALIDES; STRUCTURAL DIVERSITY; CRYSTAL-STRUCTURES; SINGLE-BOND; ORGANOANTIMONY(III); COORDINATION; TRIDENTATE; LIGAND;

D O I：

10.1039/c4dt02692f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N- and N,N,N-chelated antimony(III) and bismuth(III) chlorides L1-3MCl2 1-4 [for L-1: M = Sb (1), for L-2: M = Sb (2) and for L-3: M = Sb (3) and Bi (4)], containing ligands L1-3 derived from the pyrrole ring (where L-1 = C4H3N-2-(CH-N-2',6'-iPr(2)C(6)H(3)), L-2 = C4H2N-2,5-(CH2NMe2)(2), L-3 = C4H2N-2,5-(CH2NC4H8)(2)), were prepared by the treatment of lithium precursors with SbCl3 or BiCl3. Molecular structures of 1-4 were described both in solution (NMR spectroscopy) and in the solid state (single-crystal X-ray diffraction analysis). Structures of 1-4 were also subjected to a density functional theory study.

引用

页码：395 / 400

页数：6

共 50 条

[1] Theoretical Study on the Coordination and Separation Capacity of Macrocyclic N-Donor Extractants for Am(III)/Eu(III)
Liang, Yu Ting
Bai, Shan Qin
Zhang, Yi Ying
Li, An Yong
JOURNAL OF PHYSICAL CHEMISTRY A, 2023, 127 (33): : 6865 - 6880
[2] Theoretical study of the ability of symmetric and asymmetric N-donor ligands to separate Am(III) and Eu(III) and the bonding nature
Huang, Qijie
Wu, Shouqiang
Liang, Yu Ting
Li, An Yong
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2024, 1238
[3] A comparative spectroscopic study of U(III)/Am(III) and Ln(III) complexed with N-donor ligands
Denecke, Melissa A.
Panak, Petra J.
Burdet, Fabien
Weigl, Michael
Geist, Andreas
Klenze, Reinhardt
Mazzanti, Marinella
Gompper, Klaus
COMPTES RENDUS CHIMIE, 2007, 10 (10-11) : 872 - 882
[4] Organoantimony(III) and -bismuth(III) hypervalent pseudohalides. An experimental and theoretical study
Toma, Ana
Rat, Ciprian I.
Silvestru, Anca
Rueffer, Tobias
Lang, Heinrich
Mehring, Michael
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 745 : 71 - 79
[5] Theoretical insight on Cm(III) and Eu(III) competing with Am(III) for binding to N-donor extractants with different dentate numbers
Wu, Shouqiang
Zhang, Yiying
Li, An Yong
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2023, 123 (23)
[6] Towards the origin of effective An(III)/Ln(III) separation by tridentate N-donor ligands: a theoretical study on atomic charges and polarisabilities for Cm(III)/Gd(III) separation
Trumm, Michael
Schimmelpfennig, Bernd
MOLECULAR PHYSICS, 2016, 114 (06) : 876 - 883
[7] Synthesis and photoluminescence of three bismuth(iii)-organic compounds bearing heterocyclic N-donor ligands
Adcock, Alyssa K.
Ayscue, R. Lee, III
Breuer, Leticia M.
Verwiel, Chloe P.
Marwitz, Alexander C.
Bertke, Jeffery A.
Vallet, Valerie
Real, Florent
Knope, Karah E.
DALTON TRANSACTIONS, 2020, 49 (33) : 11756 - 11771
[8] PH metric studies on some binary complexes of dysprosium(III) and ytterbium(III) with ligands containing N,N-donor atoms
Patel, K. P.
Pabreja, D. S.
ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (01) : 817 - 819
[9] Computational thermodynamic study on the complexes of Am(III) with tridentate N-donor ligands
Liang, Yan-Ni
Yang, Xia
Ding, Songdong
Li, Shoujian
Wang, Fan
Chai, Zhifang
Wang, Dongqi
NEW JOURNAL OF CHEMISTRY, 2015, 39 (10) : 7716 - 7729
[10] Low-spin, mononuclear, Fe(III) complexes with P,N donor hemilabile ligands: A combined experimental and theoretical study
Das, Pankaj
Sarmah, Podma Pollov
Borah, Malabika
Phukan, Ashwini K.
INORGANICA CHIMICA ACTA, 2009, 362 (14) : 5001 - 5011

← 1 2 3 4 5 →