Macrokinetics of electrolysis of dilute solutions in systems with a solid polymer electrolyte

被引：0
|
作者：
Koshel', ND [1 ]
Grebenyuk, YV [1 ]
Baranova, EA [1 ]
机构：
[1] Ukrainian State Univ Chem Technol, UA-320640 Dnepropetrovsk, Ukraine
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2000年 / 36卷 / 07期
关键词：
D O I：
10.1007/BF02757677
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A model of contact between an electrode and a MF-4SK membrane in sulfuric acid solutions is studied by the impedance method. It is shown that a layer of higher electrolyte concentration forms near the free electrode surface in heavily diluted solutions. The layer ensures participation of this surface in the electrode process. Electrical fields in the region of contact between the membrane and a current collector are calculated.
引用
收藏
页码：761 / 766
页数：6
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