Water-insoluble carbonaceous components in rainwater over an urban background location in Northern India during pre-monsoon and monsoon seasons

The carbonaceous content of rainwater was investigated in samples collected at an urban background site in northern India. Sampling was performed on an event basis during two seasons: pre-monsoon (PM) and monsoon (MN) season covering May-June and July-August, respectively, in 2016. The concentrations of different fractions of water-insoluble organic carbon (WIOC) and elemental carbon (EC) were precisely determined, and the sources of WIOC and EC were also analysed. The result revealed that the average WIOC and EC concentration in rainwater ranged from 0.4 to 52 mgC/L and from 0.1 to 15.3 mgC/L, respectively. The concentrations of WIOC and EC were found to be similar to 9 times and similar to 12 times higher, respectively, in the PM season than MN season. The WIOC/EC ratio indicated higher variation in PM season as compared to that of the MN season, suggesting divergent emission sources during the PM season. The formation of water-insoluble secondary organic carbon (WISOC) has also been identified as one of the causes for the extensive difference in the WIOC/EC ratio in different seasons. Results showed that the WIOC and its fractions were efficiently scavenged through rain. While EC and its fractions were less significantly scavenged, due to its hydrophobicity and fine size. The atmospheric scavenging coefficients of selected carbonaceous components were found significantly correlated with rain intensity (RI) during both the seasons. Higher rain intensity caused greater rates of carbonaceous component wash-out and decreasing concentrations of carbonaceous components in the rain.