Rheology, Morphology, and Mechanical Properties of HMSPP/POE Blends and its Alternate Layered Foam

被引:5
|
作者
Zhao, Tianbao [1 ]
Zhang, Xianlong [1 ]
Wu, Hong [1 ]
Guo, Shaoyun [1 ]
Sun, Xiaojie [2 ]
Liang, Wenbin [2 ]
机构
[1] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
[2] Natl Inst Clean & Low Carbon Energy, Beijing 102209, Peoples R China
关键词
foams; morphology; polyolefins; properties and characterization; porous materials; POLYPROPYLENE; BEHAVIOR; FOAMABILITY; EXTRUSION; ACID);
D O I
10.1002/app.41339
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this article, the multilayered foaming sheet with alternate layered structure was successfully prepared through multilayer co-extrusion. The high melt strength polypropylene (HMSPP)/poly (ethylene-co-octene) (POE) blend and POE were designed as foaming layers and film layers, respectively. POE was added into HMSPP to reduce the crystalline degree and improve the processing performance. The rheological results indicated that the addition of POE had a little effect on relaxation process and the strain hardening behavior of HMSPP when the POE content was lower than 50%. The results of the foam morphology showed that the cell size and its distribution of the multilayered foaming sheet with alternate layers were better than that with single layer. In addition, the cell size reduced and the cell density increased with increasing the number of layers from 4 to 32. The mechanical properties of the multilayered foaming sheet with alternate layers also could be improved through assembling of foaming layers and film layers. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41339.
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页数:7
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