Addition reactions of E-E and E-H bonds to triple bond of alkynes catalyzed by Pd, Pt, and Ni complexes (E=S, Se)

被引：69
|
作者：
Beletskaya, Irina P. [1 ]
Ananikov, Valentine P.
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[2] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
PURE AND APPLIED CHEMISTRY | 2007年 / 79卷 / 06期
关键词：
addition reactions; green chemistry; transition-metal catalysis; sulfur species; selenium species;
D O I：
10.1351/pac200779061041
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthetic application and mechanistic aspects of transition-metal (Ni, Pd, Pt) catalyzed addition of E-E and E-H (E=S, Se) bonds to alkynes were investigated in detail. This study revealed major factors controlling the selectivity of such addition reactions. A new Ni-based catalytic system with a self-organized nanostructured catalyst has been designed to perform chemical transformation in high yield, under mild conditions.
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页码：1041 / 1056
页数：16
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