Synthesis and Characterization of Poly(D,L-Lactide)-Poly(Ethylene Glycol) Multiblock Poly(Ether-Ester-Urethane)s

被引:4
|
作者
Haw, Tan Ching [1 ]
Ahmad, Azizan [1 ]
Anuar, Farah Hannan [1 ]
机构
[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi 43600, Selangor Darul, Malaysia
来源
2015 UKM FST POSTGRADUATE COLLOQUIUM | 2015年 / 1678卷
关键词
Multiblock Polymer; Ring Opening Polymerization; POLYMER ELECTROLYTE; POLYLACTIDE; CONDUCTIVITY; COPOLYMERS; PEG;
D O I
10.1063/1.4931304
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this study, poly(D, L-lactide)-poly(ethylene glycol) multiblock poly(ether-ester-urethane)s was synthesized in the framework of environmental friendly products to meet the need for highly flexible polymers. Triblock copolymer with poly(ethylene glycol) as center block and poly(D, L-lactide) as side block were first synthesized by ring-opening polymerization of D, L-lactide, followed by chain extension reaction of triblocks using hexamethylene diisocyanate (HMDI). NMR and infra-red spectroscopies were used to determine the molecular composition whereas XRD analysis revealed crystallinity behavior of synthesized multiblock copolymers.
引用
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页数:7
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