Effect of Pt and Ba content on NO x Storage and Reduction Over Pt/Ba/Al2O3

被引:6
|
作者
Saito, Yoshinori [1 ]
Shimizu, Kenichi [1 ]
Nobukawa, Takeshi [2 ]
Satsuma, Atsuhshi [1 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Nagoya, Aichi 4640814, Japan
[2] Toyota Motor Co Ltd, Toyota 4718572, Japan
关键词
NOx storage reduction; Platinum; Barium; Kinetic study; Turnover frequency; SELECTIVE CATALYTIC-REDUCTION; IN-SITU FTIR; TRAP CATALYSTS; PT/BAO/AL2O3; ADSORPTION; DISPERSION; REACTIVITY; PLATINUM; PT/AL2O3; BEHAVIOR;
D O I
10.1007/s11244-010-9491-y
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Effects of Pt and Ba content of Pt/Ba/Al2O3 on NO (x) storage reduction (NSR) catalyst were investigated by means of kinetic analysis of surface nitrates using in situ FT/IR. Turnover frequencies of both storage and reduction of nitrate were significantly enhanced at higher Ba content, while those were higher at lower Pt content below 0.2 wt%.
引用
收藏
页码:584 / 590
页数:7
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