The problem of the environmental safety of road transport has become part of the security of Ukraine. The annual increase in emissions of auto-transport into the atmosphere requires stricter environmental requirements for commercial vehicles and exhaust gases of internal combustion engines. World experience shows that the use of 10-15% bioadditives in a gasoline mixture does not harm the technical and operational performance of the internal combustion engine. Besides, there are more advantages in using this type of fuel, since it is an environmentally friendly type of fuel, and it generates fewer emissions during combustion. Biofuels can be adapted to existing engine designs that will be well used in all conditions. At the same time, this fuel is better for engines; it reduces the overall cost of controlling engine pollution and, consequently, its use requires fewer maintenance costs. At the same time, modern requirements for gasoline consist in the fact that they must ensure the creation of a homogeneous fuel-air mixture of the necessary composition under any temperature conditions. This article investigates the production of high-octane gasoline A-92 and A-95 by using high-octane applications. When conducting the research used the following BodogAri: methyl tert-butyl ether (MTBE), ethanol, and isobutanol. As a basis for gasoline, catalytic cracking gasoline, catalytic reforming reformate, benzene production raffinate, straight-run gasoline, and petroleum solvent were used.