A 3-fold interpenetrating 3D Cu(II) coordination polymer based on a semi-rigid naphthalene-based bis-pyridyl-bis-amide and thiophene-2,5-dicarboxylate

被引：10
|
作者：
Wang, Xiuli [1 ]
Le, Mao [1 ]
Lin, Hongyan [1 ]
Luan, Jian [1 ]
Liu, Guocheng [1 ]
Zhang, Juwen [1 ]
Tian, Aixiang [1 ]
机构：
[1] Bohai Univ, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Dept Chem, Jinzhou 121000, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 49卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Interpenetrating network; Semi-rigid bis-pyridyl-bis-amide ligand; Fluorescent property; Selective photocatalysis; METAL-ORGANIC FRAMEWORK; DIAMONDOID NETWORK; NETS; CLUSTER;
D O I：
10.1016/j.inoche.2014.09.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D Cu(II) coordination polymer [Cu-2(4-dpna)(2)(2,5-tdca)(2)] (1) (4-dpna = N-1,N-4-di(pyridin-4-yl)naphthalene-1,4-dicarboxamide, 2,5-H(2)tdca = thiophene-2,5-dicarboxylic acid) has been hydrothermally synthesized. Complex 1 is a novel 3D metal-organic coordination complex based on a semi-rigid naphthalene-based bispyridyl-bis-amide ligand, which shows a 3-fold interpenetrating network with a CdSO4-like topology. Moreover, the fluorescent property, electrochemical behavior and selective photocatalytic activity of 1 have been investigated. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：19 / 23
页数：5
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