Transport and complex formation kinetics of polarons, dopands and bipolarons

被引:1
|
作者
Paasch, G [1 ]
Scheinert, S
机构
[1] Leibniz Inst Solid State & Mat Res, D-01171 Dresden, Germany
[2] Tech Univ Ilmenau, D-98684 Ilmenau, Germany
关键词
conjugated polymers; polarons; bipolarons; counter ions; transport;
D O I
10.1016/S0379-6779(02)00661-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bipolarons in doped polymers have usually been ignored in analyzing organic devices or electrochemical impedance measurements. For the transport in conjugated polymers Kirova and Brazovskii (Synth. Metals 76 (1996) 229) supposed the formation of complexes of polarons and bipolarons with counter ions. We formulate the theory of such scenario including traps, the direct polaron-bipolaron reaction and the formation of complexes, and analyze the possible rule of such reactions in devices.
引用
收藏
页码:407 / 408
页数:2
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