Addition of the [(tBuP)3As]- anion to the cyclopentadienyl ring of [(C5H5)M(CO)3Cl] (M = Mo, W)

被引：9

作者：

Bashall, A

Hopkins, AD

Mays, MJ

McPartlin, M

Wood, JA

Woods, AD

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b003687k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the [((BuP)-Bu-t)(3)As](-) anion with [(C5H5)M(CO)(3)Cl] (M = Mo, W) gives [(C5H4{As((PBu)-Bu-t)(3)})M(CO)(3)Cl] (M = Mo 1; M = W 2) as a result of addition to the C5H5 ring (with formal elimination of LiH), rather than the expected product resulting from substitution of the metal-bonded Cl ligand.

引用

页码：1825 / 1826

页数：2

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