A new supported rhodium catalyst for selective hydrogenation of nitriles to primary amines

被引：7
|
作者：
Witte, Peter T. [1 ]
机构：
[1] BASF Nederland BV, NL-3454 ZG De Meern, Netherlands
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2007年 / 72卷 / 04期
关键词：
selective hydrogenation; reductions; nitriles; amines; heterogeneous catalysis; rhodium;
D O I：
10.1135/cccc20070468
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nitriles are converted to primary amines with high selectivity using a newly developed alumina-supported rhodium catalyst. The high selectivity is obtained without any additives, which are often used to prevent the formation of higher amines. The catalyst is active under mild conditions in various solvents, which makes it specifically suitable for use in pharmaceutical applications or for other substrates that can react with additives like strong acids or bases.
引用
收藏
页码：468 / 474
页数：7
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