Oxidation of methanol catalyzed by silica-supported polystannazane-copper complex

被引：0
|
作者：
Tang, LM [1 ]
He, Q [1 ]
Meng, ZH [1 ]
Huang, MY [1 ]
Jiang, YY [1 ]
机构：
[1] ACAD SINICA,INST CHEM,BEIJING 100080,PEOPLES R CHINA
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 1996年 / 7卷 / 02期
关键词：
oxidation; methanol; polymer-copper complex;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Silica-supported polystannazane-copper complex has been prepared and used as a catalyst for the oxidation of methanol. The results showed that the catalyst could catalyze the oxidation of methanol to formaldehyde at a high yield and selectivity at 30 degrees C and under 1 atm mild conditions. The N/Cu mole ratio in the complex, temperature and the amount of NaOH additive had much influence on the catalytic activity. The complex was stable during the reaction and could be used repeatedly.
引用
收藏
页码：73 / 75
页数：3
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