High Performance Supercapacitors from Hierarchical Porous Carbon Aerogels Based on Sliced Bread

被引:18
|
作者
Hao, Pin [1 ]
Cui, Guanwei [1 ]
Shi, Xifeng [1 ]
Xie, Junfeng [1 ]
Xia, Xinyuan [1 ]
Sang, Yuanhua [2 ]
Wong, C. P. [3 ]
Liu, Hong [2 ]
Tang, Bo [1 ]
机构
[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci,Minist Educ,Shandon, Inst Mat & Clean Energy,Key Lab Mol & Nano Probes, Collaborat Innovat Ctr Functionalized Probes Chem, Jinan 250014, Shandong, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China
[3] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30032 USA
基金
中国国家自然科学基金;
关键词
carbon aerogel; sliced bread; supercapacitor; energy density; cycling stability; ELECTROCHEMICAL PROPERTIES; ELECTRODE MATERIALS; GRAPHENE; OXIDE; COMPOSITE; BIOPOLYMER; LAYER;
D O I
10.1002/cjoc.201600722
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supercapacitor electrodes with porous structure based on renewable, eco-friendly and cost-effective materials have caused extensive concern in energy storage fields. Sliced bread, the common food ingredient, mainly containing glucose polymers, can be a promising candidate to fabricate porous supercapacitor electrodes. Highly porous carbon aerogels by using sliced bread as the raw material were synthesized through a carefully controlled aerogel carbonization-activation process. Interestingly, the specific surface area and the pore size distribution of the porous carbon were controlled by the activation temperature, which result in the varied performance of the carbon aerogel as a supercapacitor. Electrochemical investigation measurements revealed that the hierarchical porous carbon aerogel shows an excellent capacitor behavior for construction of a symmetric supercapacitor, which demonstrated a high specific capacitance of 229 F.g(-1) at discharge current of 0.2 A.g(-1). In addition, the fabricated supercapacitor displayed excellent capacitance retention of 95.5% over 5000 cycles.
引用
收藏
页码:699 / 706
页数:8
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