Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

被引：5
|
作者：
Adamkiewicz, Malgorzata [1 ]
O'Hagan, David [1 ]
Haehner, Georg [1 ]
机构：
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 10卷
基金：
英国工程与自然科学研究理事会;
关键词：
difluoro-; dichloro-; dibromomethylenecyclopropanes; dihalocarbenes; self-assembled monolayers; surface coating; PHASE-TRANSFER CATALYSIS; C BOND; SILICON; TRIFLUOROMETHYLTRIMETHYLSILANE; IMMOBILIZATION; METATHESIS; DENSITY; THIOL;
D O I：
10.3762/bjoc.10.307
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C-C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
引用
收藏
页码：2897 / 2902
页数：6
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