Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

被引：2
|
作者：
Chan, Ka-Wang [1 ]
Ng, Wai-Ming [1 ]
Cheung, Wai-Man [1 ]
Lai, Chun-Sing [1 ]
Sung, Herman H. Y. [1 ]
Williams, Ian D. [1 ]
Leung, Wa-Hung [1 ]
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2016年 / 812卷
关键词：
Ruthenium; Nitrosyl; Thiolate; Cluster; C-S BOND; PROPARGYLIC ALCOHOLS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; NITRIC-OXIDE; CLEAVAGE; CLUSTERS; ALKYLATION; ACTIVATION; CATALYSTS;
D O I：
10.1016/j.jorganchem.2016.02.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of Ru(NO)Cl-3 with NaSC6F4H (C6F4HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H2O)(2)[Ru(NO)(SC6HF4)(2)](2)(mu-SC6HF4)(2)(mu-OH) (Na(H2O)(21)), in which the {Na(H2O)(2)}(+) moiety binds to the diruthenium core via the mu-hydroxo ligand and three ortho fluorine atoms of the thiolate ligands. Metathesis of Na(H2O)(21) with Bun(4)NBr and Ph4PCl afforded Na-free ((BunN)-N-4)[1] and (Ph4P)[1], respectively. Treatment of Ru(NO)Cl-3 with NaSBut afforded the trinuclear oxo-sulfido cluster Na(H2O)(2)[Ru(NO)(SBut)(mu-SBut)]3(mu(3)-S)(mu(3)-O) (Na(H2O)(22)) that contains a trinuclear {Ru-3(SBut)(3)} core capped by a mu(3)-oxo and a mu(3)-sulfido ligand. The {Na(H2O)(2)}(+) moiety binds to the triruthenium core via the mu 3-oxo and two terminal thiolate ligands. Metathesis of Na(H2O)(22) with (Bu4NBr)-N-n gave (Bun(4)N)[2]. Treatment of Ru(NO)Cl-3 with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)(3)(tippSH) (3). The crystal structures of Na(H2O)(21), (Ph4P)[1], and Na(H2O)(22) have been determined. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：151 / 157
页数：7
相关论文
共 50 条
  • [1] Synthesis of ruthenium-platinum di- and tri-nuclear complexes
    Yousouf, S
    Brodie, CR
    Aldrich-Wright, JR
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 96 (01) : 259 - 259
  • [2] Isolation and characterisation of stereoisomers in di- and tri-nuclear complexes
    Keene, FR
    [J]. CHEMICAL SOCIETY REVIEWS, 1998, 27 (03) : 185 - 193
  • [3] Ruthenium porphyrins containing nitrosyl, nitrosamine, thiolate, and amine ligands
    Yi, GB
    Khan, MA
    RichterAddo, GB
    [J]. INORGANIC CHEMISTRY, 1996, 35 (12) : 3453 - 3454
  • [4] Base moiety selectivity in cleavage of short oligoribonucleotides by di- and tri-nuclear Zn(II) complexes of azacrown-derived ligands
    Laine, Maarit
    Ketomaki, Kaisa
    Poijarvi-Virta, Paivi
    Lonnberg, Harri
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (13) : 2780 - 2787
  • [5] Reactions of half-sandwich rhodium(III) and iridium(III) compounds with pyridinethiolate ligands: Mono-, di-, and tri-nuclear complexes
    Wang, Hui
    Guo, Xu-Qing
    Zhong, Rui
    Lin, Yue-Jian
    Zhang, Peng-Cheng
    Hou, Xiu-Feng
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (20) : 3362 - 3368
  • [6] Bi- and tri-nuclear ruthenium(II) complexes containing tetrapyridophenazine as a rigid bridging ligand
    Bonhôte, P
    Lecas, A
    Amouyal, E
    [J]. CHEMICAL COMMUNICATIONS, 1998, (08) : 885 - 886
  • [7] Mono-, di- and tri-nuclear Ni(II) complexes of N-, O-donor ligands: structural diversity and reactivity
    Dey, M
    Rao, CP
    Saarenketo, PK
    Rissanen, K
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (11) : 924 - 928
  • [8] Di- and Tri-nuclear VIII and CrIII Complexes of Dipyridyltriazoles: Ligand Rearrangements, Mixed Valency and Ferromagnetic Coupling
    Rinck, Julia
    Kitchen, Jonathan A.
    Carter, Anthony B.
    Lan, Yanhua
    Anson, Christopher E.
    Fink, Karin
    Brooker, Sally
    Powell, Annie K.
    [J]. FRONTIERS IN CHEMISTRY, 2020, 8
  • [9] The reactivity of nitrosyl ruthenium complexes containing polypyridyl ligands
    Marília Gama Sauaia
    Roberto Santana da Silva
    [J]. Transition Metal Chemistry, 2003, 28 (3) : 254 - 259
  • [10] Mono-, di-, and tri-nuclear complexes of iron(II) with N,N,N',N'-tetramethylethylenediamine
    Davies, SC
    Hughes, DL
    Leigh, GJ
    Sanders, JR
    deSouza, JS
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (11): : 1981 - 1988
12345