Mesoporous Silica Nanoparticles Supported Atomically Precise Palladium Nanoclusters Catalyzed Aerobic Oxidation of Alcohols in Water

被引：0

作者：

Gao, Taiping ^{[1
]}

Ma, Xiaolin ^{[1
]}

Li, Xin ^{[1
]}

Xu, Qiang ^{[1
]}

Wang, Yubao ^{[1
]}

机构：

[1] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2021年 / 43卷 / 02期

关键词：

Atomically precise Palladium nanoclusters; Heterogeneous catalysis; Alcohol oxidations; Green synthesis; Aqueous media; ORGANIC-SYNTHESIS; GOLD NANOCLUSTERS; CLUSTER CATALYST; METAL-CLUSTERS; TRANSITION; CHEMISTRY; ROBUST;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first mesoporous silica nanoparticles (MSNs) supported atomically precise palladium nanoclusters catalyzed alcohol oxidation reactions in water have been achieved. The catalysts was synthesized with simple impregnation method and well characterized by TEM, FT-IR, XPS anddiffuse reflectance optical spectrum and the results proved that the Pd nanoclustersimmobilized into the pores of MSNs.The as-prepared catalyst show excellent activity for the alcohol oxidation reactions with high yield under extremely mild aqueous conditions utilizes 1 atmosphere of molecular oxygen as sole oxidant. The features of clean system, gram-scale oxidation and easy recovery catalyst make this method cost effectively and environmentally benign.

引用

页码：193 / 200

页数：8

共 50 条

[1] Mesoporous Silica Supported Au Nanoparticles with Controlled Size as Efficient Heterogeneous Catalyst for Aerobic Oxidation of Alcohols
Chu, Xuefeng
Wang, Chao
Guo, Liang
Chi, Yaodan
Gao, Xiaohong
Yang, Xiaotian
[J]. JOURNAL OF CHEMISTRY, 2015, 2015
[2] Aerobic oxidation of monoterpenic alcohols catalyzed by ruthenium hydroxide supported on silica-coated magnetic nanoparticles
Costa, Vinicius V.
Jacinto, Marcos J.
Rossi, Liane M.
Landers, Richard
Gusevskaya, Elena V.
[J]. JOURNAL OF CATALYSIS, 2011, 282 (01) : 209 - 214
[3] Aerobic oxidation of alcohols catalyzed by gold nanoparticles supported on gallia polymorphs
Su, Fang-Zheng
Chen, Miao
Wang, Lu-Cun
Huang, Xin-Song
Liu, Yong-Mel
Cao, Yong
He, He-Yong
Fan, Kang-Nian
[J]. CATALYSIS COMMUNICATIONS, 2008, 9 (06) : 1027 - 1032
[4] Size dependence in solvent-free aerobic oxidation of alcohols catalyzed by zeolite-supported palladium nanoparticles
Li, Feng
Zhang, Qinghong
Wang, Ye
[J]. APPLIED CATALYSIS A-GENERAL, 2008, 334 (1-2) : 217 - 226
[5] Selective aerobic oxidation of primary alcohols to aldehydes in functionalized mesoporous silica nanoparticles
Singappuli-Arachchige, Dilini
Manzano, J. Sebastian
Sherman, Lindy
Slowing, Igor
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[6] A Nano-Fibrillated Mesoporous Carbon as an Effective Support for Palladium Nanoparticles in the Aerobic Oxidation of Alcohols "on Pure Water"
Karimi, Babak
Behzadnia, Hesam
Bostina, Mihnea
Vali, Hojatollah
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (28) : 8634 - 8640
[7] Size-dependent catalytic activity of supported palladium nanoparticles for aerobic oxidation of alcohols
Chen, Jing
Zhang, Qinghong
Wang, Ye
Wan, Huilin
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (03) : 453 - 464
[8] Palladium Nanoparticles Supported on Titanate Nanobelts for Solvent-Free Aerobic Oxidation of Alcohols
Lu, Yong-Ming
Zhu, Hai-Zhou
Liu, Jian-Wei
Yu, Shu-Hong
[J]. CHEMCATCHEM, 2015, 7 (24) : 4131 - 4136
[9] Selective Aerobic Oxidation of Benzyl Alcohols with Palladium(0) Nanoparticles Suspension in Water
Dolorès Bourbiaux
Stéphane Mangematin
Laurent Djakovitch
Franck Rataboul
[J]. Catalysis Letters, 2021, 151 : 3239 - 3249
[10] Selective Aerobic Oxidation of Benzyl Alcohols with Palladium(0) Nanoparticles Suspension in Water
Bourbiaux, Dolores
Mangematin, Stephane
Djakovitch, Laurent
Rataboul, Franck
[J]. CATALYSIS LETTERS, 2021, 151 (11) : 3239 - 3249

← 1 2 3 4 5 →