Synthesis and adsorption properties of gold nanoparticles within pores of surface-functional porous polymer microspheres

Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface-functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylateco-acrylonitrile) and poly (EGDMA-co-AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face-centered cubic (fee) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA-co-AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. (C) 2004 Wiley Periodicals, Inc.