Structural divergence in the products of the reaction of [MoCl(η3-C3H5)(CO)2(dmpm)] with nucleophiles

被引：10

作者：

Pérez, J ^{[1
]}

Riera, V

Rodríguez, A

López, R

Sordo, TL

García-Granda, S

García-Rodríguez, E

Galindo, A

机构：

[1] Univ Oviedo, CSIC, IUQOEM, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

[2] Univ Oviedo, Fac Quim, CSIC, Dept Quim Fis & Analit, E-33071 Oviedo, Spain

[3] Univ Sevilla, Fac Quim, Dept Quim Inorgan, E-41071 Seville, Spain

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 07期

关键词：

D O I：

10.1021/om020919m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [MOCl(eta(3)-allyl)(CO)(2)(dmpm)] (dmpm = bis(dimethylphosphino)methane) (1) reacts with sodium azide and with sodium cyanide to afford the new complexes [Mo(N-3)(eta(3)-allyl)(CO)(2)(dmpm)] (2) and [Mo(CN)(eta(3)-allyl)(CO)(2)(dmpm)] (3), respectively, which were characterized spectroscopically and by X-ray diffraction. Complex 2 is a cis-dicarbonyl in which one of the P atoms of dmpm is approximately trans to a carbonyl, and the other is trans to the allyl. In contrast, 3 is a rare trans-dicarbonyl. A theoretical analysis was applied to rationalize this difference.

引用

页码：1540 / 1545

页数：6

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