Local Structural and Optical Properties of ZnO Nanoparticles

被引:25
|
作者
Jeong, Eun-Suk [1 ,2 ]
Yu, Hyo-Jong [1 ,2 ]
Kim, Yong-Jin [3 ]
Yi, Gyu-Chul [4 ]
Choi, Yong-Dae [5 ,6 ]
Han, Sang-Wook [1 ,2 ]
机构
[1] Chonbuk Natl Univ, Inst Fus Sci, Div Sci Educ, Jeonju 561756, South Korea
[2] Chonbuk Natl Univ, Inst Sci Educ, Jeonju 561756, South Korea
[3] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, Pohang 790784, South Korea
[4] Seoul Natl Univ, Natl CRI Ctr Semicond Nanorods, Seoul 151742, South Korea
[5] Seoul Natl Univ, Dept Phys, Seoul 151742, South Korea
[6] Mokwon Univ, Dept Technomkt, Taejon 302718, South Korea
关键词
EXAFS; Nanoparticle; ZnO; Structure; Photoluminescence; Quantum Confinement; ABSORPTION FINE-STRUCTURE; NANORODS; GROWTH;
D O I
10.1166/jnn.2010.2334
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This study examined the local structural and optical properties of ZnO nanoparticles (NPs) with mean diameters of 4.5 and 70 nm using extended X-ray absorption fine structure (EXAFS) measurements at the Zn K edge and photoluminescence (PL) measurements. EXAFS revealed that the average bond length of atomic pairs in the NPs was shorter than that of the powder. Furthermore, a substantial amount of structural disorder existed in the NPs. From the PL measurements, we observed the direct band gap peak of 3.41 eV from the 70 nm ZnO NPs at low temperatures. This blue shift was related to the structural property changes.
引用
收藏
页码:3562 / 3565
页数:4
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