A one-pot synthesis of novel N,N-dialkyl-S-glycosylsulfenamides

被引：11
|
作者：
Owen, DJ [1 ]
von Itzstein, M [1 ]
机构：
[1] Monash Univ, Dept Med Chem, Parkville, Vic 3052, Australia
来源：
CARBOHYDRATE RESEARCH | 2000年 / 328卷 / 03期
关键词：
sulfenamides; anomeric position; synthesis;
D O I：
10.1016/S0008-6215(00)00110-5
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
An efficient new entry into N,N-dialkyl-S-glycosylsulfenamides is reported. The reaction of bis-activated alkyl halides in the presence of a secondary amine base with glycosylic S-acetyl derivatives (1-S-acetyl-1-thioaldoses or 2-S-acetyl-2-thioketoses) results in the formation of novel carbohydrate sulfenamides. These new carbohydrate-based sulfenamides may provide useful derivatives with biological activity, as well as provide reactive carbohydrate sulfenylating agents. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：287 / 292
页数：6
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