Liquid state 15N NMR studies of 15N isotope labeled phthalocyanines

被引：1
|
作者：
Atsay, Armagan [1 ]
Gul, Ahmet [1 ]
Kocak, Makbule Burkut [1 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 01期
关键词：
Phthalocyanines; N-15; NMR; isotopic shifts; constitutional isomer; NUCLEAR-MAGNETIC-RESONANCE; SPECTROSCOPY; DERIVATIVES; SEPARATION; IRON(II);
D O I：
10.3906/kim-1506-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-15 labeled soluble metallo- and metal-free phthalocyanines are described for the first time. The complexes were synthesized starting from phthalic anhydride derivatives using 98% N-15 enriched urea. The effects of the substitution pattern, aggregation, and coordinated metal on N-15 chemical shifts in liquid state NMR were studied.
引用
收藏
页码：163 / 173
页数：11
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