Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers

被引：24
|
作者：
Babadzhanova, LA
Kirij, NV
Yagupolskii, YL
Tyrra, W
Naumann, D
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev 94, Ukraine
[2] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
TETRAHEDRON | 2005年 / 61卷 / 07期
关键词：
D O I：
10.1016/j.tet.2004.12.023
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new convenient synthetic procedure to obtain various 1, 1, 1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers has been worked out starting from anhydrides or activated esters of carboxylic acids and trimethyl(trifluoromethyl)silane in the presence of tetramethylammonium fluoride. Conditions for the selective formation of 1, 1, 1,3,3,3-hexafluoro-2-organyl-propan-2-ols as well as the trimethylsilyl derivatives have been found. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1813 / 1819
页数：7
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