Extraction of amino acids with di(2-ethylhexyl)phosphoric acid in the presence of dicyclohexyl-18-crown-6

被引:2
|
作者
Smirnova, SV [1 ]
Torocheshnikova, II [1 ]
Pletnev, IV [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
关键词
extraction; host-guest; complexation; di(2-ethylhexyl)phosphoric acid; dicyclohexyl-18-crown-6; amino acids;
D O I
10.1007/BF02494725
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Extraction of amino acids from aqueous solutions into chloroform with di(2-ethyl-hexyl)phosphoric acid was studied. The extraction efficiency decreases in the sequence Tip > Phe > Leu > Arg > Lys > lie > Ata > Gly. The addition of dicyclohexyl-18-crown-6 improves the efficiency. and kinetics of extraction of most amino acids. The extraction degree depends on the concentration of the crown ether.
引用
收藏
页码:952 / 953
页数:2
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