Selective oxidation of glycerol catalyzed by iron complexes

被引：50
|
作者：
Crotti, Corrado [1 ]
Farnetti, Erica [2 ]
机构：
[1] CNR, Ist Struttura Mat, Unita Operat Support Trieste, I-34149 Trieste, Italy
[2] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2015年 / 396卷
关键词：
Iron catalysts; Glycerol valorization; Selective oxidation; Dihydroxyacetone; FORMIC-ACID; TRANSFER HYDROGENATION; PRIMARY ALCOHOLS; REDUCTION; CONVERSION; H2O2; EPOXIDATION; KETONES;
D O I：
10.1016/j.molcata.2014.10.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Iron complexes with the polydentate ligand bis(2-pyridinylmethyl)amine (BPA) were employed as catalysts for the oxidation of glycerol using hydrogen peroxide as oxidant. The only observed reaction products were dihydroxyacetone (DHA) and formic acid. Although the overall conversion was in all cases lower than 50%, by accurate choice of the experimental conditions selectivities in DHA up to 100% were obtained. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：353 / 359
页数：7
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