Extraction and separation of gallium, indium and thallium with several carboxylic acids from chloride media

被引：80

作者：

Zhang, XY ^{[1
]}

Yin, GY ^{[1
]}

Hu, ZG ^{[1
]}

机构：

[1] Henan Normal Univ, Educ Commiss Henan, Coll Chem & Environm Sci, Key Lab Environm Sci & Engn, Xinxiang 453002, Henan, Peoples R China

来源：

TALANTA | 2003年 / 59卷 / 05期

关键词：

extraction; NA; CA-12; CA-100;

D O I：

10.1016/S0039-9140(02)00646-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method is proposed for the extraction and individual separation of trivalent gallium, indium and thallium, with sec octylphenoxy acetic acid (CA-12), sec-nonylphenoxy acetic acid (CA-100) and naphthenic acid (NA) from chloride media. The distribution equilibria of gallium (III), indium (III), thallium (III) and thallium (I) between carboxylic acids (CA-12, CA-100 and NA) dissolved in kerosene and acidic aqueous chloride media has been investigated as a function of the concentration of extractants and the concentration of hydrogen ion in aqueous phase. A possible mechanism of the extraction is discussed. The method permits rapid and precise individual separation of gallium (III), indium (III) and thallium (III), and is applicable to the analysis of alloy samples. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：905 / 912

页数：8

共 50 条

[1] CONCENTRATION AND SEPARATION OF INDIUM GALLIUM THALLIUM ANTIMONY AND BISMUTH BY EXTRACTION WITH ALKYLPHOSPHORIC ACIDS
LEVIN, IS
SHATALOVA, AA
AZARENKO, TG
VORSINA, IA
BURTOVAY.NA
RODINA, TF
[J]. TALANTA, 1967, 14 (07) : 801 - +
[2] Extraction and separation of gallium and indium from aqueous chloride solution using several organophosphorus compounds as extractants
Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka, 560-8531, Japan
[J]. J. Chem. Eng. Jpn, 5 (818-827):
[3] Extraction and separation of gallium and indium from aqueous chloride solution using several organophosphorus compounds as extractants
Nishihama, S
Hino, A
Hirai, T
Komasawa, I
[J]. JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1998, 31 (05) : 818 - 827
[4] Liquid-liquid extraction of gallium(III) from chloride media with carboxylic acids in kerosene
Zhang, XY
Yin, GY
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2002, 20 (01) : 115 - 125
[5] EXTRACTION OF GALLIUM(III) AND ITS SEPARATION FROM INDIUM(III) AND THALLIUM(III)
MULIK, GN
KUCHEKAR, SR
CHAVAN, MB
[J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1987, 64 (01) : 68 - 69
[6] SEPARATION OF GALLIUM, INDIUM AND THALLIUM BY EXTRACTION WITH N-OCTYLANILINE IN CHLOROFORM
KUCHEKAR, SR
CHAVAN, MB
[J]. TALANTA, 1988, 35 (05) : 357 - 360
[7] SOLVENT EXTRACTION AND SEPARATION OF GALLIUM(3) INDIUM(3) AND THALLIUM(3) WITH TRIBUTYLPHOSPHATE
DE, AK
SEN, AK
[J]. TALANTA, 1967, 14 (06) : 629 - &
[8] SOLVENT-EXTRACTION AND SEPARATION OF GALLIUM, INDIUM AND THALLIUM WITH N-BENZYLANILINE
KHOSLA, MML
SINGH, SR
RAO, SP
[J]. TALANTA, 1974, 21 (06) : 411 - 415
[9] COLUMN CHROMATOGRAPHIC SEPARATION OF GALLIUM, INDIUM AND THALLIUM
FRITZ, JS
FRAZEE, RT
LATWESEN, GL
[J]. TALANTA, 1970, 17 (09) : 857 - &
[10] RESIN ION EXCHANGE AND LIQUID-LIQUID EXTRACTION OF INDIUM AND THALLIUM FROM CHLORIDE MEDIA
Tereshatov, E. E.
Boltoeva, M. Yu.
Folden, C. M., III
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2015, 33 (06) : 607 - 624

← 1 2 3 4 5 →