Retention of chirality in electron-induced reactions

被引：0
|
作者：
Cheng, Fang [1 ,2 ,5 ]
Leung, Lydie [1 ,2 ]
Wang, Chen-Guang [1 ,2 ,3 ,4 ]
Ji, Wei [3 ,4 ]
Polanyi, John C. [1 ,2 ]
机构：
[1] Univ Toronto, Dept Chem, Lash Miller Chem Labs, 80 St George St, Toronto, ON M5S 3H6, Canada
[2] Univ Toronto, Inst Opt Sci, 80 St George St, Toronto, ON M5S 3H6, Canada
[3] Renmin Univ China, Dept Phys, Beijing 100872, Peoples R China
[4] Renmin Univ China, Beijing Key Lab Optoelect Funct Mat & Micronano D, Beijing 100872, Peoples R China
[5] Natl Univ Singapore, Ctr Adv Mat 2D, 1 Create Way,Create Tower, Singapore 138602, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 36期
基金：
中国国家自然科学基金; 加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
LOCALIZED ATOMIC REACTION; CHARGE DELOCALIZATION; METAL-SURFACE; REACTION LAR; SI(111) 7X7; MOLECULES; CU(110); 1,4-DIBROMOBENZENE; DISSOCIATION; HALOGENATION;
D O I：
10.1039/c6cc00849f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two enantiomers were observed by Scanning Tunneling Microscopy (STM) when meta-iodopyridine was physisorbed on a 4.6 K Cu(110) surface. The chirality of the reagent was retained in the products of the electron-induced reaction. Dynamical calculations showed this to be a consequence of the reaction occurring on one side of the mirror plane.
引用
收藏
页码：6115 / 6118
页数：4
相关论文
共 50 条
  • [1] ELECTRON-INDUCED REACTIONS ON THE DEUTERON
    MATHELITSCH, L
    CZECHOSLOVAK JOURNAL OF PHYSICS, 1993, 43 (3-4) : 363 - 386
  • [2] Electron-induced reactions of astrochemical interest.
    Arumainayagam, CR
    Lee, HL
    Cable, C
    Wilson, S
    Weeks, LD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U483 - U484
  • [3] Primary reactions in the electron-induced polymerization of acrylates
    Knolle, W
    Mehnert, R
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1995, 105 (1-4): : 154 - 158
  • [4] Electron-induced switching of the supramolecular chirality of optically active polythiophene aggregates
    Goto, H
    Yashima, E
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) : 7943 - 7949
  • [5] SYSTEMATICS OF PHOTON-INDUCED AND ELECTRON-INDUCED SPALLATION REACTIONS
    FOSHINA, M
    MARTINS, JB
    TAVARES, OAP
    DINAPOLI, V
    RADIOCHIMICA ACTA, 1989, 46 (02) : 57 - 64
  • [6] Electron-induced reactions in condensed films of acetonitrile and ethane
    Ipolyi, Imre
    Michaelis, Wilfried
    Swiderek, Petra
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (01) : 180 - 191
  • [7] Electron-Induced Reactions in 3-Bromopyruvic Acid
    da Silva, Filipe Ferreira
    Varella, Marcio T. do N.
    Jones, Nykola C.
    Hoffmann, Soren Vronning
    Denifl, Stephan
    Bald, Ilko
    Kopyra, Janina
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (21) : 5498 - 5506
  • [8] Electron-induced reactions in thin solid films of cyclopropane
    Winterling, H
    Haberkern, H
    Swiderek, P
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (20) : 4592 - 4599
  • [9] Electron-Induced Reactions of MeCpPtMe3 Investigated by HREELS
    Hedhili, M. N.
    Bredehoeft, J. H.
    Swiderek, P.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (30): : 13282 - 13286
  • [10] Bimolecular reactions on sticky and slippery clusters: Electron-induced reactions of hydrogen peroxide
    Postulka, Jan
    Slavicek, Petr
    Pysanenko, Andriy
    Poterya, Viktoriya
    Farnik, Michal
    JOURNAL OF CHEMICAL PHYSICS, 2022, 156 (05):
12345