Hydrothermal synthesis, crystal structure and electrochemical properties of the complex [Cu(o-ABA)2(2,2′-bipy)] • (H2O)

被引：0
|
作者：
Li Wei [1 ]
Li Chang-Hong
Yang Ying-Qun
Kuang Yun-Fei
机构：
[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China
[2] Hunan Inst Technol, Dept Chem Engn, Hengyang 421008, Hunan, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 23卷 / 04期
关键词：
copper (I) complex; hydrothermal synthesis; electrochemical property;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tide complex has been synthesized by o-acetamidobenzoic acid and 2,2'-bipyridine (bipy) in the mixture solvent of water and methanol. It crystallizes (C28H26CuN4O7, M-r = 594.07) in Triclinic space group P (1) over bar with a=0.805 3(4) nm, b=0.8455(4) nm, c=2.001 8(9) nm; alpha=100.797(8)degrees, beta=93.054(7)degrees, gamma=97.297(7)degrees, V=1.3239(10) nm(3), D-c=1.490 g cm(-3), Z=2. F(000)=614. R-1=0.035 9, wR(2)=0.080 5. The crystal structure shows that the copper atom is coordinated with four oxygen atoms from two o-acetamidobenzoic acid and two nitrogen atoms from the 2,2' -bipyridine, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported.
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页码：721 / 724
页数：4
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