Metal Complexes of Schiff Base Derived from Terephthalaldehyde and 2-Amino-5-Ethyl-1,3,4-Thiadiazole Synthesis, Spectral and Thermal Characterization

被引：14
|
作者：
Turan, Nevin [1 ]
Sekerci, Memet [2 ]
机构：
[1] Univ Mus Alparslan, Fac Arts & Sci, Dept Chem, TR-49100 Mus, Turkey
[2] Firat Univ, Dept Chem, Fac Arts & Sci, TR-23169 Elazig, Turkey
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 10期
关键词：
metal complexes; spectroscopy; transition metal compounds; SPECTROSCOPIC CHARACTERIZATION; COPPER(II) COMPLEXES; ZN(II) COMPLEXES; CU(II); NI(II); CO(II); NICKEL(II); MN(II); ANTIBACTERIAL; DERIVATIVES;
D O I：
10.1080/15533170903433162
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The present study deals with the preparation of Schiff base and its chelates with some transition metal ions, e.g., Co(II), Ni(II), Cu(II) and Fe(II). The structures of the ligand N-(5-ethyl-1,3,4-thiadiazole-2-yl)terephthalaldehyde imine (L) and its complexes have been synthesized and characterized by IR, 1H-NMR spectra, elemental analyses, magnetic susceptibility, UV-vis and thermogravimetry-differential thermal analysis (TGA-DTA). From the magnetic moment and UV-vis spectra data, it is found that the geometrical structures of these complexes are octahedral.
引用
收藏
页码：651 / 657
页数：7
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