A promoter effect on hydrodeoxygenation reactions of oleic acid by zeolite beta catalysts

被引：15

作者：

Azreena, I. Nur ^{[1
,3
,7
]}

Lau, H. L. N. ^{[2
]}

Asikin-Mijan, N. ^{[5
]}

Hassan, M. A. ^{[6
]}

Izham, Saiman Mohd ^{[3
,4
]}

Kennedy, E. ^{[7
]}

Stockenhuber, M. ^{[7
]}

Mastuli, M. S. ^{[8
,9
]}

Alharthi, Fahad A. ^{[10
]}

Alghamdi, Abdulaziz Ali ^{[10
]}

Taufiq-Yap, Y. H. ^{[2
,11
]}

机构：

[1] Malaysian Palm Oil Board, Biomass Technol Unit, Engn & Proc Div, 6 Persiaran Inst, Kajang 43000, Selangor, Malaysia

[2] Malaysian Palm Oil Board, Energy & Environm Unit, Engn & Proc Div, 6 Persiaran Inst, Kajang 43000, Selangor, Malaysia

[3] Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr, Serdang 43400, Selangor, Malaysia

[4] Univ Putra Malaysia, Fac Sci, Dept Chem, Serdang 43400, Selangor, Malaysia

[5] Univ Kebangsaan Malaysia, Fac Sci & Technol, Dept Chem Sci, Bangi 43600, Selangor Darul, Malaysia

[6] Univ Putra Malaysia, Fac Biotechnol & Biomol Sci, Dept Bioproc Technol, Serdang 43400, Selangor, Malaysia

[7] Univ Newcastle, Fac Engn & Built Environm, Prior Res Ctr Energy, Callaghan, NSW 2308, Australia

[8] Univ Teknol MARA, Fac Appl Sci, Sch Chem & Environm, Shah Alam 40450, Selangor, Malaysia

[9] Univ Teknol MARA, Ctr Funct Mat & Nanotechnol, Inst Sci, Shah Alam 40450, Selangor, Malaysia

[10] King Saud Univ, Chem Dept, Sci Coll, POB 2455, Riyadh 11451, Saudi Arabia

[11] Univ Malaysia Sabah, Fac Sci & Nat Resources, Kota Kinabalu 88400, Sabah, Malaysia

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2021年 / 155卷

关键词：

Biofuel; Diesel; Hydrodeoxygenation; Oleic acid; Zeolite beta; WASTE COOKING OIL; GREEN DIESEL; BIO-OIL; MODEL COMPOUNDS; PALM OIL; CRACKING; DEOXYGENATION; BIODIESEL; CO; PHENOL;

D O I：

10.1016/j.jaap.2021.105044

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this study, various metal-modified zeolite beta-based catalysts such as La(10)zeo(90), Co(10)zeo(90), Fe(10)zeo(90), Mg(10)zeo(90), Mn(10)zeo(90) and Zn(10)zeo(90) were investigated in the hydrodeoxygenation (HDO) of oleic acid (OA) to produce renewable diesel. The La(10)zeo(90) catalyst showed a conversion of OA up to 99 % with 83 % C15 and C17 selectivity after the reaction at 350 ?C for 2 h under 4 MPa H2 pressure. The superior activity of La(10)zeo(90) was attributed to the synergistic interaction between La-Si-Al, a sufficient amount of weak+ medium acid sites and excellent textural properties (large pore diameter). Larger pore diameter of La(10)zeo(90) is highly desirable as it will generate greater diffusion of bulky molecules, thereby improving the accessibility of the reactant and hence excellent catalytic activity. The vacuum distillation was used to purify the crude liquid product (CLP), producing high-quality diesel fractions mainly comprising C14, C15, and C17 fractions.

引用

页数：12

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