A novel organic-inorganic hybrid built upon molybdovanadate cluster of [V2Mo6O26]6- and {Gd(DMF)3(H2O)} units with electrochemical sensing of nitrite

被引：3

作者：

Gao, Qiao ^{[1
]}

Qi, Bin ^{[1
]}

Wu, Tingting ^{[2
]}

Xu, Lin ^{[3
]}

机构：

[1] Changchun Univ Chinese Med, Sch Pharmaceut Sci, Changchun 130117, Jilin, Peoples R China

[2] Changchun BCHT Biotechnol Co, Changchun 130012, Jilin, Peoples R China

[3] Northeast Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2019年 / 107卷

关键词：

Polyoxometalates; Organic-inorganic hybrid; Rare-earth ions; Electrochemistry;

D O I：

10.1016/j.inoche.2019.107481

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new organic-inorganic hybrid complex, [Gd(DMF)(3)(H2O)](2)[V2Mo6O26]center dot 4DMF (1) (DMF = N, N-dimethylformamide), has been synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analyses and thermogravimetric analyses. Compound 1 exhibits the sandwich type framework based on the [V2Mo6O26](6-) anion linked by two {Gd(DMF)(3)(H2O)} units from opposite sides, which is first observed in molybdovanadate system. Interestingly, electrochemical experiments demonstrate that 1-CPE exhibits good electrochemical sensing performance for sensitive detection of NO2-.

引用

页数：4

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