Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography

被引：67
|
作者：
Burgun, Alexandre [1 ,2 ]
Coghlan, Campbell J. [1 ,2 ]
Huang, David M. [1 ,2 ]
Chen, Wenqian [3 ,4 ]
Horike, Satoshi [3 ,4 ]
Kitagawa, Susumu [3 ,4 ]
Alvino, Jason F. [1 ,2 ]
Metha, Gregory F. [1 ,2 ]
Sumby, Christopher J. [1 ,2 ]
Doonan, Christian J. [1 ,2 ]
机构：
[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
[2] Univ Adelaide, Ctr Adv Nanomat, Adelaide, SA 5005, Australia
[3] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Kyoto, Japan
[4] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Kyoto, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 29期
基金：
澳大利亚研究理事会;
关键词：
carbonylation; heterogeneous catalysis; MOFs; rhodium complexes; structure elucidation; POST-SYNTHETIC METALATION; HIGH-TEMPERATURE; ADSORPTION; CARBONYLATION; METHANOL; DIMERIZATION; TRANSITION; STABILITY; CHEMISTRY; MECHANISM;
D O I：
10.1002/anie.201611254
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a Mn-II-based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of Me-I. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.
引用
收藏
页码：8412 / 8416
页数：5
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