Study on nonlinear optical, dielectric and pyroelectric properties of novel organic-inorganic hybrid material

被引:6
|
作者
Zhao, L [1 ]
Wang, SM [1 ]
Xu, ZX [1 ]
Fu, J [1 ]
Wu, CH [1 ]
Cheng, SY [1 ]
机构
[1] Hubei Univ, Sch Chem & Mat Sci, Wuhan 430062, Hubei, Peoples R China
关键词
organic-inorganic hybrid; nonlinear optics; dielectric; pyroelectric;
D O I
10.1016/S0167-577X(02)01148-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel organic and inorganic hybrid material was prepared from a nonlinear, optically active imidazole derivative, 4-(nitrophenyl)-2,4-bis-(4,4'-[N,N-bis-(2-hydroxyethyl)aminophen-yl])imidazole (NPAH4), and metal alkoxide of Ta(V) via sol-gel process. The second-order nonlinear and pyroelectric properties of the hybrid film were investigated in terms of the second harmonic generation (SHG) and pyroelectric coefficient measurement. The SHG coefficient d(33) was found to be 28.6 pm/V at the fundamental wavelength of 1064 nm and the pyroelectric coefficient P was found to be 1.6 x 10(-6) C/cm(2) K. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:2116 / 2119
页数:4
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