Carbon-Doped Mesoporous Anatase TiO2 Multi-Tubes Nanostructures for Highly Improved Visible Light Photocatalytic Activity

被引:41
|
作者
Purbia, Rahul [1 ]
Borah, Rituraj [1 ]
Paria, Santanu [1 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Interfaces & Nanomat Lab, Rourkela 769008, India
关键词
MEDIATED SYNTHESIS; BIOMORPHIC SYNTHESIS; CELLULOSE FIBERS; NANOTUBULAR SNO2; FACILE SYNTHESIS; CO2; NANOPARTICLES; MICROSPHERES; REPLICATION; REDUCTION;
D O I
10.1021/acs.inorgchem.7b01864
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Development of a high surface area and efficient visible light induced photocatalyst on a large scale is a promising task from the practical perspective. In this study, visible light active C-doped anatase TiO2 multi-tubes were synthesized using banana (Musa acuminata) stem fiber as a sacrificial template, removed by calcination at 450 degrees C. During the calcination process, the lattice of anatase TiO2 phase was doped with C, and obtained multi-tubes showed high surface area (similar to 99 m(2)/g) with a mesoporous structure made of similar to 15 +/- 3 nm nanoparticles. The synthesized TiO2 multi-tubes showed an enhanced light absorption property in the whole visible light region and good thermal stability of the anatase phase up to 750 degrees C. The synthesized C-doped TiO2 multi-tubes manifest an excellent photocatalytic activity for the reduction of Cr (VI) to Cr(III) under the visible light exposure. This process may have lots of practical importance as the method of synthesis of the catalyst is novel and the multi-tubes structure can be synthesized on a large scale through a quick and economical way with excellent photocatalytic activity. This novel multi-tubes structure may also be useful for photovoltaics, antimicrobial, and Li-batteries applications in the future.
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页码:10107 / 10116
页数:10
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