Characteristics of OH production by O2/H2O pulsed dielectric barrier discharge

被引:36
|
作者
Yao, Shuiliang [1 ]
Weng, Shan [1 ]
Tang, Yi [1 ]
Zhao, Chenwei [1 ]
Wu, Zuliang [1 ]
Zhang, Xuming [1 ]
Yamamoto, Sin [2 ]
Kodama, Satoshi [3 ]
机构
[1] Zhejiang Gongshang Univ, Sch Environm Sci & Engn, 18 Xuezheng St, Hangzhou 310018, Zhejiang, Peoples R China
[2] Res Inst Innovat Technol Earth, Chem Res Grp, 9-2 Kizugawadai, Kizugawa, Kyoto 6190292, Japan
[3] Tokyo Inst Technol, Dept Chem Engn, Meguro Ku, South Bldg 4,401C,2-12-1 Ookayama, Tokyo 1528552, Japan
基金
中国国家自然科学基金;
关键词
Dielectric barrier discharge; OH radical; Emission spectroscopy; Reaction pathway; Spatial distribution; EMISSION-SPECTROSCOPY; CORONA DISCHARGE; REACTOR; PLASMA; GENERATION; OXIDATION; MIXTURES; METHANE; OXYGEN; OZONE;
D O I
10.1016/j.vacuum.2016.01.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We studied characteristics of OH production by pulsed dielectric barrier discharge (DBD) with O-2/H2O gas mixtures. We found that the light emission from the O-2/H2O DBD was due to OH (A-X) transition. Therefore, it is allowed to measure the spatial distribution and the intensity of OH (A X) by simply direct photography of discharge image. The OH (A X) intensity became weaker approaching the dielectric barriers and away from the electrodes along the direction of the axis of and the surface of the electrodes, respectively. Regardless of the specific operating parameters, the intensity of OH (A-X) linearly increased with discharge power. At a similar level of the discharge power, increasing the applied voltage was most effective for the OH production. In addition, we found that the production of OH radical could be enhanced by increasing O(1D) radical. Our study not only introduced a simple method for the semi quantification of OH (A-X) in the O-2/H2O DBD, but also suggested a way for the optimization of OH production in a plasma process. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:16 / 23
页数:8
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